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Deprotonation-alkylation of alkyl cyanides under sonochemical conditions

Abstract : Deprotonation-alkylation of n-alkyl cyanides can be readily effected by an alkyl halide in the presence of sodium in a one pot procedure. Yields are generally better than in the usual methods, and the overall reaction conditions have important advantages in terms of ease and simplicity compatible with preparative scale-up.
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Jacques Berlan, Henri Delmas, Isabelle Duée, J. L. Luche, L. Vuiglio. Deprotonation-alkylation of alkyl cyanides under sonochemical conditions. Synthetic Communications, 1994, 24 (9), pp.1253 - 1260. ⟨10.1080/00397919408011725⟩. ⟨hal-01851814⟩



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