Development of Characterization Techniques of Thermodynamic and Physical Properties Applied to the CO2-DMSO Mixture

Abstract : This work is focused on the development of new characterization techniques of physical and thermodynamic properties. These techniques have been validated using the binary system DMSO-CO2 for which several studies of characterization have been well documented. We focused on the DMSO-rich phase and we carried out measurements of volumetric expansion, density, viscosity and CO2 solubility at 298.15, 308.15 and 313.15 K and pressures up to 9 MPa. The experimental procedures were compared and validated with the available literature data on SC-CO2-DMSO system. We made density and CO2 solubility measurements, using respectively the vibrating tube technology and two static analytical methods. Lastly, we developed an innovative falling body viscosimeter for high pressure measurements. All the measurements made are in good agreement with the already published data in spite of very different experimental techniques. This work is a contribution to the understanding of the DMSO-CO2 binary as it implements new viscosity data. Moreover, it opens new perspectives about the determination of the properties of other systems such as polymers-CO2 and fats-CO2, which are essential for supercritical process design such as extraction, crystallization, chromatography and synthesis reaction.
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Brice Calvignac, Élisabeth Rodier, Jean‐jacques Letourneau, Jacques Fages. Development of Characterization Techniques of Thermodynamic and Physical Properties Applied to the CO2-DMSO Mixture. International Journal of Chemical Reactor Engineering, De Gruyter, 2009, 7 (1), pp.A46. ⟨10.2202/1542-6580.2095⟩. ⟨hal-01142135⟩

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